Nace mr0175 and mr0103 standards metals for sulfide stress. As a form of hydrogen stress cracking, ssc is a cracking mechanism in pipelines, facilities piping and any equipment. Hydrogen sulfide is known to cause or assist in the mechanism of cracking with many alloy types including low carbon steels, low alloy steels, alloy steels, tool steels. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. School of mines and metallurgy of the university of missouri at rolla n. The role of hydrogen in sulfide stress cracking of low. Jul 25, 2017 sulfide stress cracking meaning sulfide s.
A precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. Critical nominal stress and critical stress intensity factors for sulfide stress corrosion cracking of various steels were determined using fatigueprecracked, laboratory, cantilever beam specimens and short lengths of oil field casing and tubing pressured to failure. Hydrogen stress cracking can affect several different types of metals such as high strength structural, carbon, and low alloy steels, along with titanium, nickel, and aluminium alloys. Therefore only flanges are recommended for change in material e. Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism. A study of sulfide inclusions in medium carbon steels. The required tensile stresses may be in the form of directly applied stresses or in the form of residual.
Sulfide stress corrosion cracking and hydrogen induced cracking of a216wcc wellhead flow control valve body article pdf available in case studies in engineering failure analysis. Sulphide stress cracking ssc and electrochemical testing has been undertaken on parent weldable martensitic % chromium stainless steel wmss pipe in grade lc80s api 5ct supplied by nippon steel. Sulfide stress corrosion cracking, also known as sulfide stress cracking ssc, is a stress corrosion cracking phenomena that occurs in the presence of hydrogen sulfide. Nace mr0103 carbon steel tube, iso 17945 pipe, mr0103. Sulfide stress cracking an overview sciencedirect topics.
Electrochemical and sulfide stress corrosion cracking. Pdf sulfide stress corrosion cracking and hydrogen. Sulfide stress cracking nace mr01752002, mr0175iso 15156 651 te c h n i c a l new sulfide stress cracking standard for refineries don bush, principal engineer materials, at emerson process management fisher valves, is a member and former chair of a nace task group that has written a document for refinery applications, nace mr0103. This standard nace mr0175iso 15156 addresses all mechanisms of cracking that can be caused by h2s, including below cracking conditions. Sulfide stress cracking of nickelcontaining lowalloy. It can occur when carbonsteel equipment becomes exposed to wet h2s service environments, and it can come in several different forms. Sulfide stress cracking ssc vs hydrogen induced cracking hlc posted in refining, hydrocarbons, oil, and gas. Mechanisms of alternating current induced corrosion of carbon steel publication. Sulfide stress cracking susceptibility of local hard areas. Wet hydrogen sulfide cracking is a term used for a variety of stress corrosion cracking scc failure modes of carbon steel exposed to aqueous sour refinery environments. Also, atomic hydrogen dissolved in the steel lattice may embrittle areas of hard microstructures in carbon steel base metal or weldments.
This type of cracking is referred to as stress oriented hydrogen induced cracking sohic. Carbon steel pipe nace mr0175 chemical composition has limits for substance sulfur s. Think of it as nace mr0175 for petroleum refineries. Through extensive testing it has been determined that the higher strength carbon steels are more susceptible to sulfide stress cracking. Stress corrosion cracking has been observed in absolute methanol. Methanolinduced corrosion is a type of corrosion induced by methanol. During investigation many cracks were observed on the inner surface of the valve body grown from the. Highnickel alloys abrass aluminum alloys titanium alloys magnesium alloys zirconium alloys environment hot nitrate, hydroxide, and carbonatebicarbonate solutions. Sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism.
It is a form of hydrogenrelated cracking and can have two distinct morphologies. Material selection for sour service environment pipeline. Hydrogen induced cracking hic is a form of tiny blistering damage caused by a high concentration of hydrogen in steel. Jul 10, 2019 methanolinduced corrosion is a type of corrosion induced by methanol. The reason is that these dissimilar welds will always contain high hardness zones, which are susceptible to sulfide stress cracking.
Surface studies of ultra strength drilling steel after. More extensive use of the wet fluorescent magnetic particle technique in recent years as a refinery equipment inspection tool has highlighted the extent and magnitude of the. H 2 s can cause sulfide stress cracking of stainless steels. Mr01032005 materials resistant to sulfide stress cracking in corrosive petroleum refining environments. In that article, we concluded that while localized corrosion appears to be a prerequisite for anodic eac modes such as stress corrosion cracking scc, hydrogenassisted eac mechanisms like hydrogen stress cracking hsc are exacerbated at cathodic potentials. This large scale test program, sponsored by the refining.
In this environment, not only is hydrogen sulfide stress cracking a concern, but the presence of. Sulfide stress cracking susceptibility of local hard areas in carbon. Sulfide stress cracking ssc galvanically induced hydrogen stress cracking. Nace mr0175 seamless pipe, cs pipe nace mr0175, iso 15156. Hydrogen sulfide cracking of carbon and alloy steels. Our sour service grades ss are designed to prevent sulfide stress cracking ssc failures when used in the appropriate domain. The three main factors of sulfide stress corrosion cracking are stress level, environment and temperature.
Nanostructured steel susceptibility to sulfide stress cracking. Sulfide stress cracking of highstrength steels in laboratory. As we know that both form of cracking are due to the absorption of atomic hydrogen that is produced by. Only stateoftheart facilities can achieve this result. Residual stresses can be relieved by stressrelief annealing, and this is widely used for carbon steels. Stress corrosion cracking facts and how to reduce the. Sulfide stress cracking nace mr01752002, mr0175iso 15156. Pdf sulfide stress corrosion cracking and hydrogen induced.
It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism. Hydrogen sulfide gas properties and safety with h2s. Ssc is a form of hydrogen stress cracking resulting from absorption of atomic hydrogen that is produced by the sulfide corrosion reaction on the metal surface. This paper presents results from a testing program designed to investigate sulfide stress cracking susceptibility of local hard areas in weld heat affected zones evaluated by 4point bend testing. The need for more adequate engineering data and a better theoretical understanding of sulfide cracking has led to a more thorough study of several variables involved in the sulfide cracking of carbon steel.
Documenting equipment have been attributed oo these forms of corrosive damage. In susceptible alloys, the hydrogen combines with carbon. In the solution containing high pressure co2, cr, and p110 steels exhibited general. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. However, the methods discussed above cannot be used to. Sulfide stress cracking ssc vs hydrogen induced cracking. Nace mr0103 is a new standard entitled materials resistant to sulfide stress cracking in corrosive petroleum refining environments. Sulfide stress cracking is most severe at ambient temperature, particularly in the range of 20 to 120f 6 to 49c. However, hydrogen sulfide forms a weak acid when dissolved in water. Weldable martensitic % chromium stainless steels wmss are used for mildly sour welded flowlines in the oil and gas industry as an alternative to inhibited carbon steel or lined pipe. Hudgins c, mcglasson rl, mehdlzadeh p, rosborough wm. Hardness, yield strength, stress and microstructure were the. Carbon steels in service in the offshore and oil refinery industries are susceptible to a cracking mechanism known as sulfide stress cracking ssc or hydrogen stress cracking hsc when in sour service, ie when hydrogen sulfide h 2 s is present in the process fluid.
Dec 19, 2019 sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism. The most common forms of wet h 2s cracking are hydrogen induced cracking hic, stressoriented hydrogen induced cracking sohic, and sulfide stress cracking ssc. Sulfide stress cracking susceptibility of local hard areas in. But my question is, is residual stress generated during normal welding practice is a determining factor in ssc. Pwht of piping components in sour service metal and. Element performs sulfide stress cracking ssc testing of metals subject to cracking under the combined action of tensile stress and corrosion in the presence of water and h2s, in compliance with nace tm0177 iso 15156 standards. This term should not be confused with stress corrosion cracking scs, since this is anodic in nature.
Wet hydrogen sulfide h2s cracking inspectioneering. Cross section of a carbon steel ferritepearlite specimen showing hydrogen induced cracking hic. Sulfide stress cracking of nickelcontaining lowalloy steels microbially influenced corrosion of steels by oxidative degradation and corrosiveness of biodiesel. Rp04032003 avoiding caustic stress corrosion cracking of carbon steel refinery equipment and piping.
Material considerations when working with hydrogen 3. Jan 08, 2002 sulfide stress corrosion cracking occurs due to conjoint action of chloride and hydrogen sulfide, presence of tensile stresses and nonlinear relationship with temperature. An industry value that has been developed is nace mr01, 2003, from the national association of corrosion engineers. Water with hydrogen sulfide alone does not cause disease. Hardness, yield strength, stress and microstructure were the primary metallurgical variables studied. Ian sutton, in plant design and operations second edition, 2017. It involves the ingress of hydrogen into a component, an event that can seriously reduce the ductility and loadbearing capacity, cause cracking and catastrophic brittle failures at stresses below the yield stress of susceptible materials. Sulfide stress cracking effects high strength effects high strength carbon steels above rockwell hardness 22 especially in petroleum production and petroleum refining. Small alloying additions to carbon steel generate materials with improved general corrosion resistance but often poorer resistance to ssc environments. Highnickel alloys abrass aluminum alloys titanium alloys magnesium alloys zirconium alloys environment hot nitrate, hydroxide, and. Surface flaws also influence the hydrogen cracking or sulfide stress cracking of moderate to highstrength steels exposed to brine containing h2s. Sscc is a specialized case of hydrogen cracking as it may be possible that sulfide stress corrosion cracking and hydrogen cracking proceed simultaneously. Ssc, hydrogen sulfide near the surface of the steel breaks down during the corrosion reaction into atomic hydrogenh and iron sulphidesi. H2s can cause sulfide stress cracking of stainless steels.
Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. On the evaluation method of sulfide stress cracking susceptibility of carbon and low alloy steels. Sulfide stress corrosion cracking of steels corrosion. The electrochemical and sulfide stress corrosion cracking sscc behaviors of cr stainless steel and p110 steel were investigated in a simulated acidic annular environment with lowtemperature and highpressure h2sco2 using electrochemical methods, ubend immersion tests, and scanning electron microscopy. The blistering damage tends to form parallel to the. For solutions with a methanol content of 50% or more, the. Evaluation of the seabed temperature corrosion and sulphide. What is nace mr0175iso 15156 steel pipe and fittings. Ferritic stainless steels, on the other hand, tend to be fairly resistant to hydrogen stress cracking due to their comparatively low hardness. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. This is a complex topic, other factors, such as ph, chloride concentration, and temperature also affect the potential for steel cracking.
Corrosion under sulfide deposits on copper piping in treated water 009 top crevice corrosion of copper tubes in air 010. Corrosion of epoxycoated aluminium fins in marine atmosphere 001. Corrosionpedia what is sulfide stress cracking ssc. In this case the solution is to use low alloy steels with addition of cr, mo. The valve body alloy was a216wcc cast carbon steel. High atomic hydrogen concentrations in carbon steel can lead to sulfide stress cracking ssc of these hard areas. The improved resistance to ssc is obtained through a specific design of the steel chemistry and a tight control of microstructure and mechanical properties. Element sulfide stress cracking ssc testing according the nace tm0177 iso 15156 standards help ensure sour service pipelines reliability and longevity. Although the cracking is described as stress cracking, the main problem is the hardness of the parent metal. Nace mr0175 was originally created to cover sulfide stress cracking in the oil and gas production industry.
The first type is commonly referred to as hydrogen induced cracking hic and can occur where little or no applied or residual tensile stress exists. Sulfide stress cracking nicontaining steels transformation start temperature, i. Is sulfide stress cracking an anodic or a cathodic process. Sulfide stress cracking nace mr01752002, mr0175iso. It is a recognized problem in the gas and oil industries, pipelines, municipal sewage treatment systems, and a variety of industrial applications. Susceptible alloys, especially steels, react with hydrogen sulfide, forming.
Other factors, such as ph, chloride concentration, and temperature also affect the potential for steel cracking. Exposure of carbon steel equipment to wet h 2 s service environments can lead to various forms of attack, e. Standard material requirements materials resistant to. It can act as a catalyst in the absorption of atomic hydrogen in steel, promoting sulfide stress cracking. H 2 s can cause corrosion of stainless steels such as 316 and 410 stainless in the form of sulfide stress cracking. Stress corrosion cracking facts and how to reduce the risk. Susceptible alloys, especially steels, react with hydrogen sulfide, forming metal sulfides and atomic hydrogen as corrosion byproducts. This is a type of deterioration which can be linked to corrosion and corrosioncontrol processes. Factors affecting the sulfide stress cracking performance of. Material considerations when working with hydrogen. Sulfide stress cracking ssc stress corrosion cracking. Sulfide stress cracking susceptibility of local hard areas in carbon steel weld heat affected zones.
In susceptible alloys, the hydrogen combines with carbon within the alloy. The most common forms of wet h 2 s cracking are hydrogen induced cracking hic, stress oriented hydrogen induced cracking sohic, and sulfide stress cracking ssc. Sulfide stress cracking of nickelcontaining lowalloy steels. In a previous post, we discussed the broad differences between anodic and cathodic forms of environmentally assisted cracking eac. Nanostructured steel, sulfide stress corrosion cracking, notch tensile slow strain test method introduction hydrogen embrittlement assisted cracking hec continues to be a significant concern for many major industries 14. Therefore, it is a source of hydrogen ions and is corrosive. Evaluation of the seabed temperature corrosion and. Girth welds were made in astm a694 grade f60 and a350 grade lf2 carbon steel materials.
Assuring compliance in sour service applications due to the hazardous nature of sour service applications, which contain hydrogen sulfide h2s, the national association of corrosion engineers nace has issued a standard recommended practice that includes minimum requirements to resist sulfide stress cracking. Below 20f 6c the diffusion rate of the hydrogen is figure 1. Wet h 2 s cracking can occur in susceptible steels exposed to aqueous environments containing hydrogen sulfide. Since strength of steel parallels its hardness, the empirically determined maximum hardness specified in rc22. Equation 3 shows that carbon has the largest effect on ms temperature, followed by mn, ni, and cr. The api specification 5ct lists two steel grades, l80, and c95 which have a restricted yield strength range of 15,000 psi. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. In carbon steel nace mr0103 pipes hydrogen sulfide isnt just a poisonous gas, but also can cause stress corrosion cracking in alloys and steels. Nace mr0175 seamless pipe, cs pipe nace mr0175, iso 15156 2.